2NO(g) + 2H2(g) → N2(g) + 2H2O(g) 6.0×10^4 M^-2 s^-1
다음 반응을 생각해 보자.
2NO(g) + 2H2(g) → N2(g) + 2H2O(g)
(a) 이 반응의 속도 법칙은 H2에 대하여 일차이고
NO에 대하여 이차이다. 속도 법칙을 쓰시오.
(b) 반응의 속도 상수가 1000 K에서
6.0×10^4 M^-2 s^-1이라고 하면,
[NO] = 0.035 M이고 [H2] = 0.015 M일 때의
반응 속도는 얼마인가?
(c) 1000 K에서 NO의 농도가 0.10 M로 증가하고
H2의 농도가 0.010 M일 때의 반응 속도는 얼마인가?
(d) 1000 K에서 [NO]가 0.010 M로 감소하고
[H2]가 0.030 M로 증가할 때의 반응 속도는 얼마인가?
Consider the following reaction:
2NO(g) + 2H2(g) → N2(g) + 2H2O(g)
(a) The rate law for this reaction is first order in H2
and second order in NO. Write the rate law.
(b) If the rate constant for this reaction
at 1000 K is 6.0×10^4 M^-2 s^-1,
what is the reaction rate
when [NO] = 0.035 M and [H2] = 0.015 M?
(c) What is the reaction rate at 1000 K
when the concentration of NO is increased to 0.10 M,
while the concentration of H2 is 0.010 M?
(d) What is the reaction rate at 1000 K
if [NO] is decreased to 0.010 M
and [H2] is increased to 0.030 M?
(a) The rate law for this reaction is first order in H2 and second order in NO. Write the rate law.
rate = k [NO]^2 [H2]
(b) If the rate constant for this reaction at 1000 K is 6.0×10^4 M^-2 s^-1, what is the reaction rate when [NO] = 0.035 M and [H2] = 0.015 M?
rate = k [NO]^2 [H2]
= (6.0×10^4) (0.035)^2 (0.015)
= 1.1025 M/s
≒ 1.1 M/s
(c) What is the reaction rate at 1000 K when the concentration of NO is increased to 0.10 M, while the concentration of H2 is 0.010 M?
rate = k [NO]^2 [H2]
= (6.0×10^4) (0.10)^2 (0.010)
= 6.0 M/s
(d) What is the reaction rate at 1000 K
if [NO] is decreased to 0.010 M
and [H2] is increased to 0.030 M?
rate = k [NO]^2 [H2]
= (6.0×10^4) (0.010)^2 (0.030)
= 0.18 M/s
[ 관련 글 https://ywpop.tistory.com/22591 ]
NO와 H2의 농도가 모두 2.0×10^(-6) mol L-1일 때,
반응 속도가 7.86×10^(-3) mol L-1 s-1이라면,
이 반응의 속도 상수 값과 단위는?
[키워드] 2NO(g) + 2H2(g) → N2(g) + 2H2O(g) 기준, 2NO(g) + 2H2(g) → N2(g) + 2H2O(g) rate law
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